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New Version of Carbon Harder than Diamond

Lin Wang of Carnegie Institution for Science has observed a new form of carbon which is harder than diamond.

Carbon is the fourth-most-abundant element in the universe and the basis of all life we know.  It takes on a wide variety of forms including graphene, graphite, diamond, cylindrical nanotubes, and hollow spheres called fullerenes.

Forms of carbon are generally either crystalline or amorphous. In crystalline forms the structure is organized in repeating atomic units. Amorphous structures lack the long-range order of crystals. Hybrid products that combine both crystalline and amorphous elements had not previously been observed, although scientists believed they could be created.

Wang's team, including Carnegie's Wenge Yang, Zhenxian Liu, Stanislav Sinogeikin, and Yue Meng, started with a carbon-60 cages, made of highly organized balls of carbon constructed of pentagon and hexagon rings bonded together to form a round, hollow shape. A solvent was put into the spaces between the balls and a new structure formed. They then applied pressure to this combination of carbon cages and solvent, to see how it changed under different stresses.

At relatively low pressure, the carbon-60's cage structure remained. But as the team increased the pressure, the cage structures started to collapse into more amorphous carbon clusters. However, the amorphous clusters still occupy their original sites, forming a lattice structure.

The team discovered that there is a narrow window of pressure, about 320,000 times the normal atmosphere, under which this new structured carbon is created and does not bounce back to the cage structure when pressure is removed. This is crucial for finding practical applications for the new material going forward.

This material was capable of indenting the diamond anvil used in creating the high-pressure conditions. This means that the material is superhard.

If the solvent used to prepare the new form of carbon is removed by heat treatment, the material loses its lattice periodicity, indicating that that the solvent is crucial for maintaining the chemical transition that underlies the new structure. Because there are many similar solvents, it is theoretically possible that an array of similar, but slightly different, carbon lattices could be created using this pressure method.

"We created a new type of carbon material, one that is comparable to diamond in its inability to be compressed," Wang said. "Once created under extreme pressures, this material can exist at normal conditions, meaning it could be used for a wide array of practical applications."

The research was published in Science on August 17.

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